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International Journal of Automotive Technology > Volume 25(4); 2024 > Article
International Journal of Automotive Technology 2024;25(4): 745-754.
doi: https://doi.org/10.1007/s12239-024-00088-6
DE-NOx/CO Performance According to Ag Loading Amount and Support Type of H2-SCR
Choong-kil Seo
Department of Automotive & Mechanical Engineering, Howon University
PDF Links Corresponding Author.  Choong-kil Seo , Email. ckseo@howon.ac.kr
ABSTRACT
This study aims to investigate the NOx/CO reduction characteristics of harmful gases according to the loading amount of active Ag, which plays the most important role in H2-SCR, and the type of support. H2-SCR with Ag loaded on support of TiO2 was reduced to Ag+ at about 140 °C in AgO oxide, and H2-SCR with Ag loaded on support of Al2O3 was reduced to Ag clusters (Agnδ+) at about 260 °C in AgO oxide. Because it is more unstable than AgO oxide, it promoted the chemical reaction of Ag. 0.5Ag/TiO2 H2-SCR showed the highest NOx conversion rate of about 18% at 200 °C, and the window width was also widened. 2Ag/Al2O3 H2-SCR improved the low-temperature activity of the catalyst due to its large specific surface area and the loading amount of active catalyst Ag. Although the harmful gas reduction performance has decreased significantly compared to the active material Pt used in the H2-SCR, research on active materials considering the performance the improvement and economic feasibility must be continued.
Key Words: Catalyst · Nitrogen oxide · Selective catalytic reduction · Carbon monoxide · Ag

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